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Well, the mix needs to be strong enough to be effective. Once the spray gets absorbed into the fur, the smell usually neutralizes fairly readily. I have not had a problem with diluted Apple Cider Vinegar preventing my cats from grooming, but I suppose some cats may object to it.
The apple cider vinegar spray looks promising, except don't cats hate vinegar? Won't he likely stop grooming himself? Or, how about ingesting the vinegar if he does groom, harmful or no?
I just whipped up a batch and put it in a spray bottle; it's still mighty strong smelling even diluted.
Apple Cider Vinegar is not toxic to cats, and in small doses, has been used as an occasional tonic and to relieve constipation.